PUBLICATIONS

Please click on the title or picture for a link to the paper.

21. SPECIATION AND PHOTOLUMINESCENT PROPERTIES OF A 2,6-BIS(PYRROL-2-YL)PYRIDINE IN THREE PROTONATION STATES

Dylan C. Leary, Jordan C. Martinez, Anitha S. Gowda, Novruz G. Akhmedov, Jeffrey L. Petersen and Carsten Milsmann

ChemPhotoChem 2023, available online

20. ORGANOMETALLIC INTERMEDIATES IN THE SYNTHESIS OF PHOTOLUMINESCENT ZIRCONIUM AND HAFNIUM COMPLEXES WITH PYRIDINE DIPYRROLIDE LIGANDS

Dylan C. Leary, Yu Zhang, Jose G. Rodriguez, Novruz G. Akhmedov, Jeffrey L. Petersen, Brian S. Dolinar, and Carsten Milsmann

Organometallics 2023, available online

19. LONG-LIVED PHOTOLUMINESCENCE FROM AN EIGHT-COORDINATE ZIRCONIUM(IV) COMPLEX WITH FOUR 2-(2’-PYRIDYL)PYRROLIDE LIGANDS

Dylan C. Leary, Jordan C. Martinez, Novruz G. Akhmedov, Jeffrey L. Petersen and Carsten Milsmann

Chemical Communications 2022, 58, 11917

18. CARBENE TRANSFER FROM A PYRIDINE DIPYRROLIDE IRON–CARBENE COMPLEX: REVERSIBLE MIGRATION OF A DIPHENYLCARBENE LIGAND INTO AN IRON–NITROGEN BOND

Brett M. Hakey, Dylan C. Leary, Jordan C. Martinez, Jonathan M. Darmon, Novruz G. Akhmedov, Jeffrey L. Petersen, and Carsten Milsmann

Organometallics 2022, 41, 2268

17. LONG-LIVED PHOTOLUMINESCENCE OF MOLECULAR GROUP 14 COMPOUNDS THROUGH THERMALLY ACTIVATED DELAYED FLUORESCENCE

Anitha S. Gowda, Tia S. Lee, Michael C. Rosko, Jeffrey L. Petersen, Felix N. Castellano, and Carsten Milsmann

Inorganic Chemistry 2022, 61, 7338

16. SYNTHESIS AND CHARACTERIZATION OF PYRIDINE DIPYRROLIDE URANYL COMPLEXES

Brett M. Hakey, Dylan C. Leary, Lauren M. Lopez, Leyla R. Valerio, William W. Brennessel, Carsten Milsmann, and Ellen M. Matson

Inorganic Chemistry 2022, 61, 6182

15. HIGH MAGNETIC ANISOTROPY OF A SQUARE-PLANAR IRON-CARBENE COMPLEX

Brett M. Hakey, Dylan C. Leary, Jin Xiong, Caleb F. Harris, Jonathan M. Darmon, Jeffrey L. Petersen, John F. Berry, Yisong Guo, Carsten Milsmann

Inorganic Chemistry 2021, 60, 18575

14. EFFECTS OF 2,6-DICHLOROPHENYL SUBSTITUENTS ON THE COORDINATION CHEMISTRY OF PYRIDINE DIPYRROLIDE IRON COMPLEXES

Brett M. Hakey, Dylan C. Leary, Jose G. Rodriguez, Jordan C. Martinez, Nicholas B. Vaughan, Jonathan M. Darmon, Novruz G. Akhmedov, Jeffrey L. Petersen, Brian S. Dolinar, Carsten Milsmann

Zeitschrift für anorganische und allgemeine Chemie 2021, 647, 1503

13. LOW POWER THRESHOLD PHOTOCHEMICAL UPCONVERSION USING A ZIRCONIUM(IV) LMCT PHOTOSENSITIZER

Mo Yang, Sara Sheykhi, Yu Zhang, Carsten Milsmann, Felix N. Castellano

Chemical Science 2021, 12, 9069

12. EFFECTS OF LIGAND SUBSTITUTION ON THE OPTICAL AND ELECTROCHEMICAL PROPERTIES OF (PYRIDINEDIPYRROLIDE)ZIRCONIUM PHOTOSENSITIZERS

Yu Zhang, Dylan C. Leary, Anne M. Belldina, Jeffrey L. Petersen, and Carsten Milsmann

Inorganic Chemistry 2020, 59, 14716

11. PHOTOCHEMICAL SYNTHESIS OF A ZIRCONIUM CYCLOBUTADIENYL COMPLEX

P. Minh N. Do, Novruz G. Akhmedov, Jeffrey L. Petersen, Brian S. Dolinar, Carsten Milsmann

Chemical Communications 2020, 56, 5397

10. DELAYED FLUORESCENCE FROM A ZIRCONIUM(IV) PHOTOSENSITIZER WITH LIGAND-TO-METAL CHARGE-TRANSFER EXCITED STATES

Yu Zhang, Tia S. Lee, Joseph M. Favale, Dylan C. Leary, Jeffrey L. Petersen, Gregory D. Scholes, Felix N. Castellano, Carsten Milsmann

Nature Chemistry 2020, 12, 345

9. REACTIVITY OF PYRIDINE DIPYRROLIDE IRON (II) COMPLEXES WITH ORGANIC AZIDES: C-H AMINATION AND IRON TETRAZENE FORMATION.

Brett M. Hakey, Jonathan M. Darmon, Novruz G. Akhmedov, Jeffrey L. Petersen, and Carsten Milsmann

Inorganic Chemistry 2019, 58, 11028

8. SEVEN-COORDINATE ZIRCONIUM AND HAFNIUM COMPLEXES WITH 2,2'-PYRIDYLPYRROLIDE LIGANDS

Yu Zhang, Novruz G. Akhmedov, Jeffrey L. Petersen, and Carsten Milsmann

Chemistry - A European Journal 2019, 25, 3042

7. SYNTHESIS AND ELECTRONIC STRUCTURE OF NEUTRAL SQUARE-PLANAR HIGH-SPIN IRON(II) COMPLEXES SUPPORTED BY A DIANIONIC PINCER LIGAND

Brett M. Hakey, Jonathan M. Darmon, Yu Zhang, Jeffrey L. Petersen, and Carsten Milsmann

Inorganic Chemistry 2019, 58, 1252

6. PHOTOCHEMICAL C–C BOND FORMATION IN LUMINESCENT ZIRCONIUM COMPLEXES WITH CNN PINCER LIGANDS

Yu Zhang, Jeffrey L. Petersen, and Carsten Milsmann

Organometallics 2018, 37, 4488

5. A ZIRCONIUM PHOTOSENSITIZER WITH A LONG-LIVED EXCITED STATE: MECHANISTIC INSIGHT INTO PHOTOINDUCED SINGLE-ELECTRON TRANSFER

Yu Zhang, Tia S. Lee, Jeffrey L. Petersen, and Carsten Milsmann

Journal of the American Chemical Society 2018, 140, 5934

4. SYNTHESIS OF A CYCLOPHANE BEARING TWO BENZ[A]ANTHRACENE UNITS CONNECTED AT THE 5 AND 7 POSITIONS WITH TWO NAPHTH-1,4-DIYL GROUPS

Haresh Thakellapalli, Behzad Farajidizaji, Shuangjiang Li, Josef C. Heller, Yu Zhang, Novruz G. Akhmedov, Carsten Milsmann, Jeffrey L. Petersen, Kung K. Wang

The Journal of Organic Chemistry 2018, 83, 2455

3. REDOX CHEMISTRY OF BIS(PYRROLYL)PYRIDINE CHROMIUM AND MOLYBDENUM COMPLEXES: AN EXPERIMENTAL AND DENSITY FUNCTIONAL THEORETICAL STUDY

Anitha S. Gowda, Jeffrey L. Petersen, Carsten Milsmann

Inorganic Chemistry 2018, 57, 1919

2. SYNTHESIS AND STRUCTURE OF A FUNCTIONALIZED [9]CYCLOPARAPHENYLENE BEARING THREE INDENO[2,1-A]FLUORENE-11,12-DIONE-2,9-DIYL UNITS

Shuangjiang Li, Merfat Aljhdli, Haresh Thakellapalli, Behzad Farajidizaji, Yu Zhang, Novruz G. Akhmedov, Carsten Milsmann, Brian V. Popp, Kung K. Wang

Organic Letters 2017, 19, 4078

1. A LUMINESCENT ZIRCONIUM(IV) COMPLEX AS A MOLECULAR PHOTOSENSITIZER FOR VISIBLE LIGHT PHOTOREDOX CATALYSIS

Yu Zhang, Jeffrey L. Petersen, Carsten Milsmann

Journal of the American Chemical Society 2016, 138, 13115

PRIOR TO WVU

35. N−N BOND CLEAVAGE OF 1,2-DIARYLHYDRAZINES AND N−H BOND FORMATION VIA H-ATOM TRANSFER IN VANADIUM COMPLEXES SUPPORTED BY A REDOX-ACTIVE LIGAND

Carsten Milsmann, Scott P. Semproni, Paul J. Chirik

Journal of the American Chemical Society 2014, 136, 12099

34. FOUR-COORDINATE COBALT PINCER COMPLEXES: ELECTRONIC STRUCTURE STUDIES AND LIGAND MODIFICATION BY HOMOLYTIC AND HETEROLYTIC PATHWAYS

Scott P. Semproni, Carsten Milsmann, Paul J. Chirik

Journal of the American Chemical Society 2014, 136, 9211

33. SYNTHESIS, ELECTRONIC STRUCTURE AND REACTIVITY OF BIS(IMINO)PYRIDINE IRON CARBENE COMPLEXES: EVIDENCE FOR A CARBENE RADICAL

Sarah K. Russell, Jordan M. Hoyt, Suzanne C. Bart, Carsten Milsmann, S. Chantal E. Stieber, Scott P. Semproni, Serena DeBeer, Paul J. Chirik

Chemical Science 2014, 5, 1168

32. CATALYTIC HYDROGENATION ACTIVITY AND ELECTRONIC STRUCTURE DETERMINATION OF BIS(ARYLIMIDAZOL-2-YLIDENE)PYRIDINE COBALT ALKYL AND HYDRIDE COMPLEXES

Renyuan Yu, Jonathan M. Darmon, Carsten Milsmann, Grant Margulieux, S. Chantal E. Stieber, Serena DeBeer, Paul J. Chirik

Journal of the American Chemical Society 2013, 135, 13168

31. REVERSIBLE CARBON-CARBON BOND FORMATION INDUCED BY OXIDATION AND REDUCTION AT A REDOX-ACTIVE COBALT COMPLEX

Crisita C. H. Atienza, Carsten Milsmann, Scott P. Semproni, Zoe R. Turner, Paul J. Chirik

Inorganic Chemistry 2013, 52, 5403

30. REDOX-INDUCED N2 HAPTICITY SWITCHING IN ZIRCONOCENE DINITROGEN COMPLEXES

Scott P. Semproni, Donald J. Knobloch, Carsten Milsmann, Paul J. Chirik

Angewandte Chemie International Edition 2013, 52, 5372

29. OXIDATION AND REDUCTION OF BIS(IMINO)PYRIDINE IRON DINITROGEN COMPLEXES: EVIDENCE FOR FORMATION OF A CHELATE TRIANION

Aaron M. Tondreau, S. Chantal E. Stieber, Carsten Milsmann, Emil Lobkovsky, Thomas Weyhermüller, Paul J. Chirik

Inorganic Chemistry 2013, 52, 635

28. SPIN CROSSOVER IN A 3,5-BIS(2-PYRIDYL)-1,2,4-TRIAZOLATE-BRIDGED DINUCLEAR IRON(II) COMPLEX [{FE(NCBH3)(PY)}2(Μ-L1)2] – POWDER VERSUS SINGLE CRYSTAL STUDY

Caspar J. Schneider, John D. Cashion, Nicholas F. Chilton, Celine Etrillard, Mauricio Fuentealba, Judith A. K. Howard, Jean-Francois Létard, Carsten Milsmann, Boujemaa Moubaraki, Hazel A. Sparkes, Stuart R. Batten, Keith S. Murray

European Journal of Inorganic Chemistry 2013, 850

27. SYNTHESIS, ELECTRONIC STRUCTURE AND ALKENE HYDROSILYLATION ACTIVITY OF TERPYRIDINE AND BIS(IMINO)PYRIDINE IRON DIALKYL COMPLEXES

Aaron M. Tondreau, Crisita Carmen Hojilla Atienza, Jonathan M. Darmon, Carsten Milsmann, Helen M. Hoyt, Keith J. Weller, Susan A. Nye, Kenrick M. Lewis, Julie Boyer, Johannes G. P. Delis, Emil Lobkovsky, Paul J. Chirik

Organometallics 2012, 31, 4886

26. AZO N=N BOND CLEAVAGE WITH A REDOX-ACTIVE VANADIUM COMPOUND INVOLVING METAL-LIGAND COOPERATIVITY

Carsten Milsmann, Zoe R. Turner, Scott P. Semproni, Paul J. Chirik

Angewandte Chemie International Edition 2012, 51, 5386

25. SIDE-ON DINITROGEN COMPLEXES OF TITANOCENES WITH DISUBSTITUTED CYCLOPENTADIENYL LIGANDS: SYNTHESIS, STRUCTURE AND SPECTROSCOPIC CHARACTERIZATION

Scott P. Semproni, Carsten Milsmann, Paul J. Chirik

Organometallics 2012, 31, 3672

24. STRUCTURE AND REACTIVITY OF A HAFNOCENE Μ-NITRIDE PREPARED FROM DINITROGEN CLEAVAGE

Scott P. Semproni, Carsten Milsmann, Paul J. Chirik

Angewandte Chemie International Edition 2012, 51, 5213

23. BIS(IMINO)PYRIDINE IRON DINITROGEN COMPOUNDS REVISITED: DIFFERENCES IN ELECTRONIC STRUCTURE BETWEEN FOUR- AND FIVE-COORDINATE DERIVATIVES

S. Chantal E. Stieber, Carsten Milsmann, Jordan M. Hoyt, Zoe R. Turner, Kenneth D. Finkelstein, Karl Wieghardt, Serena DeBeer, Paul J. Chirik

Inorganic Chemistry 2012, 51, 3770

22. SYNTHESIS AND ELECTRONIC STRUCTURE DETERMINATION OF N-ALKYL-SUBSTITUTED BIS(IMINO)PYRIDINE IRON IMIDES EXHIBITING SPIN CROSSOVER BEHAVIOR

Amanda C. Bowman, Carsten Milsmann, Eckhard Bill, Zoe R. Turner, Emil Lobkovsky, Serena DeBeer, Karl Wieghardt, Paul J. Chirik

Journal of the American Chemical Society 2011, 133, 17353

21. SYNTHESIS, ELECTRONIC STRUCTURE AND ETHYLENE POLYMERIZATION ACTIVITY OF BIS(IMINO)PYRIDINE COBALT ALKYL CATIONS

Crisita C. H. Atienza, Carsten Milsmann, Emil Lobkovsky, Paul J. Chirik

Angewandte Chemie International Edition 2011, 50, 8143

20. OXIDATION AND REDUCTION OF BIS(IMINO)PYRIDINE DICARBONYL COMPLEXES

Oxidation and Reduction of Bis(imino)pyridine Dicarbonyl Complexes.

Aaron M. Tondreau, Carsten Milsmann, Emil Lobkovsky, Paul J. Chirik

Inorganic Chemistry 2011, 50, 9888

19. SPIN STATES AND REDOX CHANGES IN IRON BIS-TERDENTATE NITROXIDE {NNO} CHELATES

Murray, K., Gass, I., Gartshore, C., Lupton, D., Moubaraki, B., Nafady, A., Bond, A., Boas, J., Cashion, J., Milsmann, C., Wieghardt, K.

Inorganic Chemistry 2011, 50, 3052

18. SYNTHESIS, ELECTRONIC STRUCTURE AND CATALYTIC ACTIVITY OF REDUCED BIS(ALDIMINO)PYRIDINE IRON COMPOUNDS: EXPERIMENTAL EVIDENCE FOR LIGAND PARTICIPATION

Sarah K. Russell, Carsten Milsmann, Emil Lobkovsky, Thomas Weyhermüller, Paul J. Chirik

Inorganic Chemistry 2011, 50, 3159

17. SYNTHESIS AND ELECTRONIC STRUCTURE OF CATIONIC, NEUTRAL AND ANIONIC BIS(IMINO)PYRIDINE IRON ALKYL COMPLEXES: EVALUATION OF REDOX ACTIVITY IN SINGLE COMPONENT ETHYLENE POLYMERIZATION CATALYSTS

Tondreau, A. M., Milsmann, C., Patrick, A. D., Hoyt, H. M., Lobkovsky, E., Wieghardt, K., Chirik, P. J.

Journal of the American Chemical Society 2010, 132, 15046

16. REDUCED N-ALKYL SUBSTITUTED BIS(IMINO)PYRIDINE COBALT COMPLEXES: MOLECULAR AND ELECTRONIC STRUCTURES FOR COMPOUNDS VARYING BY THREE OXIDATION STATES

Amanda C. Bowman, Carsten Milsmann, Eckhard Bill, Emil Lobkovsky, Thomas Weyhermüller, Karl Wieghardt, Paul J. Chirik

Inorganic Chemistry 2010, 49, 6110

15. STABILIZATION OF HIGH-VALENT FEIVS6-CORES BY DITHIOCARBAMATE(1-) AND 1,2-DITHIOLATE(2-) LIGANDS IN OCTAHEDRAL [FEIV(ET2DTC)3-N(MNT)N](N-1)- COMPLEXES (N = 0, 1, 2, 3). A SPECTROSCOPIC AND DENSITY FUNCTIONAL THEORY COMPUTATIONAL STUDY

Milsmann, C., Sproules, S., Bill, E., Weyhermüller, T., DeBeer George, S., Wieghardt, K.

Chemistry - A European Journal 2010, 16, 3628

14. SYNTHESIS, MOLECULAR AND ELECTRONIC STRUCTURES OF REDUCED BIS(IMINO)PYRIDINE COBALT DINITROGEN COMPLEXES: LIGAND VERSUS METAL REDUCTION

Bowman, A. C., Milsmann, C., Hojilla Atienza, C. C., Lobkovsky, E., Wieghardt, K., Chirik, P. J.

Journal of the American Chemical Society 2010, 132, 1676

13. REVERSIBLE P4 ACTIVATION WITH NICKEL(I) AND A Η3-COORDINATED TETRAPHOSPHORUS LIGAND BETWEEN TWO NI(I) CENTERS

Yao, S., Xiong, Y., Milsmann, C., Bill, E., Pfirrmann, S., Limberg, C., Driess, M.

Chemistry - A European Journal 2010, 16, 436

12. ELECTRONIC STRUCTURES OF [RUII(CYCLAM)(ET2DTC)]+, [RU(CYCLAM)(TDT)]+, AND [RU(CYCLAM)(TDT)]2+. AN X-RAY ABSORPTION SPECTROSCOPIC AND COMPUTATIONAL STUDY (TDT = TOLUENE-3,4-DITHIOLATE; ET2DTC = N,N-DIETHYLDITHIOCARBAMATE(1-))

Milsmann, C., Bill, E., Weyhermüller, T., DeBeer George, S., Wieghardt, K.

Inorganic Chemistry 2009, 48, 9754

11. OCTAHEDRAL MONODITHIOLENE COMPLEXES OF IRON: CHARACTERIZATION OF S,S′-COORDINATED DITHIOLATE(1-) Π RADICAL MONOANIONS. A SPECTROSCOPIC AND DENSITY FUNCTIONAL THEORETICAL INVESTIGATION

Milsmann, C., Patra, G. K., Bill, E., Weyhermüller, T., DeBeer George, S., Wieghardt, K.

Inorganic Chemistry 2009, 48, 7430

10. OCTAHEDRAL MONODITHIOLENE COMPLEXES OF COBALT(III) AND CHROMIUM(III). SPECTROSCOPIC AND DENSITY FUNCTIONAL THEORETICAL CHARACTERIZATION OF S,S´-COORDINATED BENZENE-1,2-DITHIOLATE(1-) Π RADICALS

Milsmann, C., Bothe, E., Bill, E., Weyhermüller, T., Wieghardt, K.

Inorganic Chemistry 2009, 48, 6211

9. FACILE DISSOCIATION OF [(LNIII)2E2] DICHALCOGENIDES (E = SE, TE): EVIDENCE FOR [LNIIIE2] SUPERSELENIDES AND SUPERTELLURIDES IN SOLUTION

Yao, S., Xiong, Y., Zhang, X., Milsmann, C., Schwarz, H., Driess, M.

Angewandte Chemie International Edition 2009, 48, 4551

8. REDUCTION CHEMISTRY OF ARYL- AND ALKYL-SUBSTITUTED BIS(IMINO)PYRIDINE IRON DIHALIDE COMPOUNDS: MOLECULAR AND ELECTRONIC STRUCTURES OF [(PDI)2FE]

Wile, B. M., Trovitch, R. J., Bart, S. C., Tondreau, A. M., Lobkovsky, E., Milsmann, C., Bill, E., Wieghardt, K., Chirik, P. J.

Inorganic Chemistry 2009, 48, 4190

4. A "SIDE-ON" SUPEROXONICKEL COMPLEX [LNI(O2)] WITH A SQUARE-PLANAR TETRACOORDINATE NICKEL(II) CENTER AND ITS CONVERSION INTO [LNI(Μ-OH)2NIL]

Yao, S., Bill, E., Milsmann, C., Wieghardt, K., Driess, M.

Angewandte Chemie International Edition 2008, 47, 7110

3. FROM A PARAMAGNETIC, MONONUCLEAR SUPERSULFIDONICKEL(II) COMPLEX TO A DIAMAGNETIC DIMER WITH A FOUR-SULFUR TWO-ELECTRON BOND

Yao, S., Milsmann, C., Bill, E., Wieghardt, K., Driess, M.

Journal of the American Chemical Society 2008, 130, 13536

2. ONE- AND TWO-ELECTRON REDUCED 1,2-DIKETONE LIGANDS IN [ZNII(L•)2(ET2O)], [COII(L•)2(ET2O)], AND NA2(ET2O)4[COII(LRED)2]

Spikes, G. H., Milsmann, C., Bill, E., Weyhermüller T., Wieghardt, K.,

Inorganic Chemistry 2008, 47, 11745

1. CHARGE DISTRIBUTION IN CHROMIUM AND VANADIUM CATECHOLATO COMPLEXES: X-RAY ABSORPTION SPECTROSCOPIC AND COMPUTATIONAL STUDY

Milsmann, C., Levina, A. Harris, H. H., Foran, G. J., Turner, P., Lay, P. A.

Inorganic Chemistry 2006, 45, 4743